Drogba struck the only goal of the night in first-half stoppage time as
Roberto di Matteo's men shut out the defending champions at Stamford
Bridge.
The Catalans dominated possession throughout but could not find a way past Petr Cech in the Chelsea goal.
Alexis Sanchez lobbed against the bar in the first half before
substitute Pedro curled a low shot against the post in stoppage time.
Former Arsenal midfielder Cesc Fabregas also had a shot cleared off the
line by Ashley Cole as Pep Guardiola's side controlled possession in
trademark fashion.
But, with the mercurial Lionel Messi kept quiet by a disciplined home
defence, the visitors could not make the breakthrough to leave Chelsea
with a slim lead ahead of next week's second leg at the Nou Camp.
Drogba was preferred to Fernando Torres in attack and - as he had in the
FA Cup semi-final against Tottenham at the weekend - he vindicated the
decision with the match-winning moment.
The Ivorian had spent most of the first period on the floor nursing
numerous injuries but was on his feet to drive in the 45th-minute
strike.
Messi gave the ball away in the centre circle and Frank Lampard switched play with a fine pass to release Ramires down the left.
Ramires was then able to pick out Drogba lurking at the back post and
the striker hit his left-footed shot under Victor Valdes and into the
net.
Barca captain Carles Puyol almost rescued an equaliser in the final
minutes but Cech brilliantly clawed out his close-range header, before
Pedro curled a shot against the post in stoppage time.
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